How do i move S-video to secondary monitor then primary?

Q: Is it possible to use S-video with TV as a secondary monitor other then showing up the primary monitor? i finally got the S-video to work for me but the thing is that S-video is set on primary monitor and it shows up on TV like what i see right now. Is there a way to set my S-video to a secondary monitor instead of showing the primary? i want to still do my work right now and yet turn on a full scream movie connected with the S-video to the TV is there a way? i tried everything, turning on the secondary monitor but shows only primary? is there a way please. help

A: I have an ATI display card and i have my TV set as secondary if you have ATI catalyst control center you can set it up there.

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